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Selective photocatalytic C–C bond cleavage under ambient conditions with earth abundant vanadium complexes
Selective C–C bond cleavage under ambient conditions is a challenging chemical transformation that can be a valuable tool for organic syntheses and macromolecular disassembly. Herein, we show that base metal vanadium ...
Reversible [4 + 2] cycloaddition reaction of 1,3,2,5-diazadiborinine with ethylene
Under ambient conditions, a [4 + 2] cycloaddition reaction of 1,3,2,5-diazadiborinine 1 with ethylene afforded a bicyclo[2.2.2] derivative 2, which was structurally characterized. The cyclization process was found to be ...