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Stibine-protected Au 13 nanoclusters : syntheses, properties and facile conversion to GSH-protected Au 25 nanocluster
Monostibine-protected ionic Au13 nanoclusters, namely, [Au13(L)8(Cl)4][Cl] (L= SbPh3, 2a·Cl; Sb(p-tolyl)3, 2b·Cl) were prepared by the direct reduction of Au(L)Cl with NaBH4 in dichloromethane. Anion exchange with 2a·Cl ...
Synthesis and reactivity of cationic iridium aminocarbenes derived from terminal alkynes and 2-aminopyridines
The reaction of a terminal alkyne (RCCH) and 2- aminopyridine (R′C5NH3NH2) with the dinuclear species [Cp*IrCl2]2 afforded the cationic aminocarbene derivatives Cp*Ir(Cl)[ C- (CH2R)NHC5NH3R′] via a hydroamination and ...