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Binuclear oxidative addition of Sb-Cl bonds : a facile synthetic route to main group transition element clusters and rings
Binuclear oxidative addition of Sb–Cl bonds with the clusters Os3(CO)11(NCCH3), 1, or Os3(CO)10(NCCH3)2, 2, was found to be an effective synthetic route to organometallic clusters and rings containing μ2-SbPh2 or μ3-SbPh ...
Oxidative addition across Sb–H and Sb–Sb bonds by an osmium carbonyl cluster : trapping the intermediate
The cluster Os3(CO)11(NCCH3) oxidatively adds across the Sb–H bond in SbPh2H to afford the clusters Os3(CO)11(H)(μ-SbPh2) and Os3(CO)11(μ-H)(μ-SbPh2)Os3(CO)11. Similarly, its reaction with Sb2Ph4 afforded Os3(CO)11(μ-SbP ...