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Stibine-protected Au 13 nanoclusters : syntheses, properties and facile conversion to GSH-protected Au 25 nanocluster
Monostibine-protected ionic Au13 nanoclusters, namely, [Au13(L)8(Cl)4][Cl] (L= SbPh3, 2a·Cl; Sb(p-tolyl)3, 2b·Cl) were prepared by the direct reduction of Au(L)Cl with NaBH4 in dichloromethane. Anion exchange with 2a·Cl ...
The metallostibine Os2(CO)8(μ-SbPh) : a versatile donor precursor for antimony-containing heterometallic clusters
The metallostibine Os2(CO)8(μ-SbPh), 2, acts as a good two-electron donor ligand, reacting readily with Group 8 metal carbonyls to give heterometallic clusters. Specifically, it undergoes ligand substitution reaction with ...