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Kinetics and DFT studies of photoredox carbon–carbon bond cleavage reactions by molecular vanadium catalysts under ambient conditions
Visible light assisted photocatalytic organic reactions have recently received intense attention as a versatile approach to achieve selective chemical transformations, including C−C and several C−X (X = N, O, S) bond ...
Selective photocatalytic C–C bond cleavage under ambient conditions with earth abundant vanadium complexes
Selective C–C bond cleavage under ambient conditions is a challenging chemical transformation that can be a valuable tool for organic syntheses and macromolecular disassembly. Herein, we show that base metal vanadium ...
Reversible [4 + 2] cycloaddition reaction of 1,3,2,5-diazadiborinine with ethylene
Under ambient conditions, a [4 + 2] cycloaddition reaction of 1,3,2,5-diazadiborinine 1 with ethylene afforded a bicyclo[2.2.2] derivative 2, which was structurally characterized. The cyclization process was found to be ...
Bisguanidinium dinuclear oxodiperoxomolybdosulfate ion pair-catalyzed enantioselective sulfoxidation
Catalytic use of peroxomolybdate for asymmetric transformations has attracted increasing attention due to its catalytic properties and application in catalysis. Herein, we report chiral bisguanidinium dinuclear ...