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The original reactivity of a phosphole-substituted Fischer carbene complex
In an unprecedented transformation, a phosphole-substituted Fischer carbene complex reacts with styrene to give an annelated phosphole derivative.
A new type of phosphaferrocene–pyrrole–phosphaferrocene P-N-P pincer ligand
A 2-ethoxycarbonylphosphaferrocene was reduced to the corresponding 2-hydroxymethyl derivative, which was condensed with pyrrole in a 2:1 ratio in the presence of BF3 to give a phosphaferrocene–pyrrole–phosphaferrocene ...
Generation and reactivity of methylphosphaketene in the coordination sphere of tungsten
The [4 + 2] cycloadduct between the 1-methyl-2-keto-1,2-dihydrophosphinine pentacarbonyltungsten complex and dimethyl acetylenedicarboxylate can be used as a precursor for the methylphosphaketene tungsten complex under UV ...
Activation of a 1-chlorophosphirane complex by aluminum trichloride : generation and trapping of [Fc-P-W(CO)5] (Fc = Ferrocenyl)
Aluminum trichloride catalyzes the ring opening of a 1-chlorophosphirane W(CO)5 complex and its reaction with thiophene and ferrocene to give the corresponding 1-(2-thienyl)- and 1-ferrocenylphosphirane derivatives. The ...