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Spectroscopic characterization and mechanistic studies on visible light photoredox carbon–carbon bond formation by bis(arylimino)acenaphthene copper photosensitizers
Currently, the most popular molecular photosensitizers used for synthetic organic chemistry and energy applications are still the noble metal-based ruthenium and iridium complexes that usually require expensive metal and ...
Stibine-protected Au 13 nanoclusters : syntheses, properties and facile conversion to GSH-protected Au 25 nanocluster
Monostibine-protected ionic Au13 nanoclusters, namely, [Au13(L)8(Cl)4][Cl] (L= SbPh3, 2a·Cl; Sb(p-tolyl)3, 2b·Cl) were prepared by the direct reduction of Au(L)Cl with NaBH4 in dichloromethane. Anion exchange with 2a·Cl ...
The metallostibine Os2(CO)8(μ-SbPh) : a versatile donor precursor for antimony-containing heterometallic clusters
The metallostibine Os2(CO)8(μ-SbPh), 2, acts as a good two-electron donor ligand, reacting readily with Group 8 metal carbonyls to give heterometallic clusters. Specifically, it undergoes ligand substitution reaction with ...
Molecular engineering toward coexistence of dielectric and optical switch behavior in hybrid perovskite phase transition material
Organic–inorganic hybrid perovskites with considerable dielectric differences near the phase transition are potential candidates as phase transition materials (PTMs). However, compared with traditional PTMs, which require ...