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Synthesis and electronic properties of novel 5,7-diazapentacene derivatives
A route to the synthesis of novel 5,7‐diazapentacenes and some preliminary studies on their properties is reported. A single crystal X‐ray diffraction study of the dihexyl derivative showed it had formed a dimer during the ...
Cobalt complex of a tetraamido macrocyclic ligand as a precursor for electrocatalytic hydrogen evolution
Hydrogen (H2) is a clean fuel that can potentially store renewable energy and overcome some of the environmental problems that arise from fossil-fuel consumption. One attractive approach is to produce H2 from water ...
Visible light driven hydrogen evolution by molecular nickel catalysts with time-resolved spectroscopic and DFT insights
Hydrogen (H2) is a clean fuel that can potentially be a future solution for the storage of intermittent renewable energy. However, current H2 production is mainly dominated by the energy intensive steam reforming reaction, ...
Hydrophobic metal halide perovskites for visible-light photoredox C-C bond cleavage and dehydrogenation catalysis
Two-dimensional lead and tin halide perovskites were prepared by intercalating the long alkyl group 1-hexadecylammonium (HDA) between the inorganic layers. We observed visible-light absorption, narrow-band photoluminescence, ...