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Stibine-protected Au 13 nanoclusters : syntheses, properties and facile conversion to GSH-protected Au 25 nanocluster
Monostibine-protected ionic Au13 nanoclusters, namely, [Au13(L)8(Cl)4][Cl] (L= SbPh3, 2a·Cl; Sb(p-tolyl)3, 2b·Cl) were prepared by the direct reduction of Au(L)Cl with NaBH4 in dichloromethane. Anion exchange with 2a·Cl ...
Molecular engineering toward coexistence of dielectric and optical switch behavior in hybrid perovskite phase transition material
Organic–inorganic hybrid perovskites with considerable dielectric differences near the phase transition are potential candidates as phase transition materials (PTMs). However, compared with traditional PTMs, which require ...