Now showing items 1-5 of 5
Kinetics and DFT studies of photoredox carbon–carbon bond cleavage reactions by molecular vanadium catalysts under ambient conditions
Visible light assisted photocatalytic organic reactions have recently received intense attention as a versatile approach to achieve selective chemical transformations, including C−C and several C−X (X = N, O, S) bond ...
Synthesis and the optical and electrochemical properties of indium(III) bis(arylimino)acenaphthene complexes
Aryl bis(imino)acenaphthenes (Ar-BIANs) are well-established rigid and sterically bulky diimine ligands, which are redox-noninnocent and versatile π-acceptors due to their low-lying π* orbitals and are frequently used to ...
New insights into the photocatalytic activity of 3-D core–shell P25@silica nanocomposites : impact of mesoporous coating
In this report, a three-dimensional (3-D) network of core–shell TiO2 (P25)–mesoporous SiO2 (P25@mSiO2) nanocomposites was prepared via a controllable surfactant-assisted sol–gel method. The nanocomposites were investigated ...
Mechanistic insights for the photoredox organocatalytic fluorination of aliphatic carbons by anthraquinone using time-resolved and DFT studies
Chemoselective photoredox fluorination is an appealing approach to access fluorinated fine chemicals such as active pharmaceutical ingredients, but most of the known procedures currently lack time-resolved mechanistic ...
Bay-region functionalisation of Ar-BIAN ligands and their use within highly absorptive cationic iridium(III) dyes
We report the synthesis, UV-vis absorption, electrochemical characterisation, and DFT studies of five panchromatic, heteroleptic iridium complexes (four of which are new) supported by Ar-BIAN ligands. In particular, the ...